0.1 mol each of ethyl alcohol and acetic acid one allowed to react and at equilibrium the acid was exactly neutralized by 100ml of 0.75 n naoh
Answers
Answer:
Answer
{ CH }_{ 3 }COOH+{ C }_{ 2 }{ H }_{ 5 }OH\rightleftharpoons { CH }_{ 3 }COO{ C }_{ 2 }{ H }_{ 5 }+{ H }_{ 2 }OCH
3
COOH+C
2
H
5
OH⇌CH
3
COOC
2
H
5
+H
2
O
0.1 0.1 0 0 Before reaction
(0.1-x)(0.1−x) (0.1-x)(0.1−x) xx xx
mEq of of acetic aid left = mEq of NaOH used = 100 x 0.85 = 85
\therefore∴ Millimoles of aetic acid left = 85 (\because \quad mono\quad basic)(∵monobasic)
\therefore Moles\, of \,acetic\, acid\, left = 0.085∴ Molesofaceticacidleft=0.085
(0.01-x)=0.085(0.01−x)=0.085
x=0.015x=0.015
Now,
$${ K }_{ C }=\displaystyle\frac { { x }^{ 2 } }{ { (0.1-x) }^{ 2 } }
=\frac { { (0.015) }^{ 2 } }{ { (0.085) }^{ 2 } } =0.031$$
Answer:
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