0•278 g of magnesium when dissolved in dilute HCI evolved 218•2 mL
of hydrogen at 17°C and 754.5 mm collected over water Find the equivalent weight of the metal
ve (Vapour pressure of water at 17°C = 14.4 mm).
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Answer:
Mole of H
2(n)
=
RT
PV
=
760×1000×0.0821×293
(780.4−17.4)×119.7
=5×10
−3
Let eq. wt. of metal be E.
Eq. of metal = Eq. of H
2
E
0.275
= mole of H
2
×2=2×5×10
−3
E=27.52
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