0.532 gram of chloroplatinate of an organic base
(mol wt. 244) gave 0.195 gram of platinum on ignition.
The number of nitrogen atoms per molecule of base is
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4
Explanation:
molecular weight of choloplatinate = 244u
therefore,
2B+H2PtCl6--------->B2H2PtCl2-------(on heat)---->Pt
equivalent wt = 2B+2+195+(6*35.5)
= 2B + 410
[wt of chloroplatinate/wt of platinum] = [equivalent wt of salt/equivalent wt pt]
0.532/0.195 = 2B+410/195
therefore,
E = 61
therefore number of nitrogen atoms per molecule of base= 244/61=4
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