0.7 g of iron combines directly with 0.4 g ofsulphur to form ferrous sulphide. If 2.8 g of iron are dissolved in dilute HCI & excess ofsodium sulphide solution is added, 4.4g. of iron sulphide are precipitated. Does thedata illustrated the law of constant
composition?
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Hello dear!
According to law of constant composition a pure chemical compound contains the same elements in the fixed proportion of their weights regardless the mode of preparation.
In the first line, the ratio of weights (R₁) of iron(Fe) and sulphur(S) will be:
Fe : S : : 0.7 : 0.4
Fe : S : : 7 : 4
∵ 2.8 g of iron gives 4.4 g ferrous sulphide precipitate.
So, Amount of sulphur combines with 2.8 g iron = 4.4 - 2.8 = 1.6 g.
Now,
The ratio of weights will be: (R₂)
Fe : S : : 2.8 : 1.6
Fe : S : : 7 : 4
∵ R₁ = R₂ (The ratio of two elements in both the compounds is equal).
Hence, It follows the law of constant composition.
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