1.5 kg of a gas expands within an elastic container from 100 kPaa and 150 liters to a final pressure of 8 kPaa. If the process is defined by pV1.25 = C and the internal energy decreases by 30 kJ/kg, calculate the heat transferred in kJ
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Answer:
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Given info : 1.5 kg of a gas expands within an elastic container from 100 kPa and 150 liters to a final pressure of 8 kPa. If the process is defined by pV1.25 = C and the internal energy decreases by 30 kJ/kg.
To find : The heat transferred in kJ.
solution : given
so,
here, P₁ = 100 kPa , V₁ = 150 Litres, P₂= 8 kPa and V₂ = ?
so, 100 × (150)^(1.25) = 8 × V₂^(1.25)
⇒12.5 × (150)^(1.25) = V₂^(1.25)
⇒(12.5)^(1.25) × 150 = V₂
⇒V₂ = 3525.5654 Litres ≈ 3525.6 litres
using formula, work done in quasi - static process is given by, when
so, Workdone , W= (100 × 150 - 3525.6 × 8)/(1.25 - 1)
= -13204.8/0.25
= -52819.2 kPa . litre
= -52819.2 × 10¯³ kJ
= -52.8192 kJ ≈ -53 kJ
internal energy change, ∆U = ∆U/∆m × m
= 30 kJ/kg × 1.5 kg
= 45 kJ
by first law of thermodynamics,
Q = ∆U + W
⇒Q = 45 kJ + (-53 kJ) = -8 kJ
therefore the heat transferred from system is 8 kJ.