1 calculate the ratio of rate constants at room temperature
for two reactions that have the same A value but have E
values that differs by I k cal mol-1
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Did you mean: 1 calculate the ratio of rate constants at room temperature for two reactions that have the same A value but have E values that differ by I k cal mol-1
Answer:
NO.1:
Ap - E / RT , = exp ( Calculate E , for a reaction whose rate constant at room temperature is doubled by a 10 - °C increase in T . Then repeat the calculation for a reaction whose rate constant is ... 10 Effect of E , on k BE K 310 / k 300 Calculate the room - temperature ratio of the rate constants for two reactions that have the same A value but have E , values that differ by ( a ) 1 kcal / mol ; ( b ) 10 kcal / mol .
NO.2:
( Unimolecular decompositions of compounds with strong bonds have very high E , values ; for example , E , is 100 kcal / mole for the gas - phase decomposition CO2 → CO + O . ) An upper limit on observed E , values is set by the fact that reactions with extremely high ... 2 / R1 = exp - a , 2 - Ea , 1 Calculate the room - temperature ratio of the rate constants for two reactions that have the same A value but have En values that differ by ( a ) 1 kcal / mole ; ( b ) 10 kcal / mole .
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