1. Give balanced equations to obtain carbon monoxide:
(i) By dehydration of an organic acid.
(ii) Reduction of a metal oxide.
(iii) By oxidation of a nonmetal.
(iv) Reduction of a non-metallic oxide.
Answers
Answer:
All nonmetals form covalent oxides with oxygen, which react with water to form acids or with bases to form salts. Most nonmetal oxides are acidic and form oxyacids, which in turn yield hydronium ions (H3O+) in aqueous solution. There are two general statements that describe the behaviour of acidic oxides. First, oxides such as sulfur trioxide (SO3) and dinitrogen pentoxide (N2O5), in which the nonmetal exhibits one of its common oxidation numbers, are known as acid anhydrides. These oxides react with water to form oxyacids, with no change in the oxidation number of the nonmetal; for example,
N2O5 + H2O → 2HNO3.
Second, those oxides in which the metal does not exhibit one of its common oxidation numbers, such as nitrogen dioxide (NO2) and chlorine dioxide (ClO2), also react with water. In these reactions, however, the nonmetal is both oxidized and reduced (i.e., its oxidation number is increased and decreased, respectively). A reaction in which the same element is both oxidized and reduced is called a disproportionation reaction. In the following disproportionation reaction, N4+ is reduced to N2+ (in NO) and oxidized to N5+ (in HNO3).
3NO2 + H2O → 2HNO3 + NO
Oxides of nitrogen
The oxides of nitrogen. chemical compound
Explanation:
Nitrogen (N) forms oxides in which nitrogen exhibits each of its positive oxidation numbers from +1 to +5. Nitrous oxide (dinitrogen oxide), N2O, is formed when ammonium nitrate, NH4NO3, is heated. This oxide, which is a colourless gas with a mild, pleasant odour and a sweet taste, is used as an anesthetic for minor operations, especially in dentistry. It is called laughing gas because of its intoxicating effect. It is also widely used as a propellant in aerosol cans of whipped cream. Nitric oxide, NO, can be created in several ways. The lightning that occurs during thunderstorms brings about the direct union of nitrogen and oxygen in the air to produce small amounts of nitric oxide, as does heating the two elements together. Commercially, nitric oxide is produced by burning ammonia (NH3), whereas in the laboratory it can be produced by the reduction of dilute nitric acid (HNO3) with, for example, copper (Cu).
3Cu + 8HNO3 → 2NO + 3Cu(NO3)2 + 4H2O
Gaseous nitric oxide is the most thermally stable oxide of nitrogen and is also the simplest known thermally stable paramagnetic molecule—i.e., a molecule with an unpaired electron. It is one of the environmental pollutants generated by internal-combustion engines, resulting from the reaction of nitrogen and oxygen in the air during the combustion process. At room temperature nitric oxide is a colourless gas consisting of diatomic molecules. However, because of the unpaired electron, two molecules can combine to form a dimer by coupling their unpaired electrons.
2NO ⇌ N2O2
Thus, liquid nitric oxide is partially dimerized, and the solid consists solely of dimers.
When a mixture of equal parts of nitric oxide and nitrogen dioxide, NO2, is cooled to −21 °C (−6 °F), the gases form dinitrogen trioxide, a blue liquid consisting of N2O3 molecule
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