1. The maximum number of molecules are present in:
[AIPMT-2004]
(a) 5L of N2 gas at STP
(b) 0.5g of H2 gas (c) 10g of O2 gas
(d) 15L of H2 gas at STP
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Formula
- n = moles
- w = mass
- m = molar mass
- M = molecules
- V = volume
Solution:-
(a)
Volume of N 2 (V)= 5 L
we know that ,
⟹ n = V / 22.4 L
⟹ n = 5 / 22.4
⟹ n = 0.22
we know that ,
⟹ n = M / 6.023 x 10²³
On rearranging ,
⟹ M = 0.22 x 6.023 x 10²³
⟹ M = 1.32 x 10²³
(b)
- Mass of H2 = 0.5 g
- Molar mass of H 2 = 2
From the formulae we can conclude that ,
⟹w / m = M / 6.023 x 10²³
On rearranging ,
⟹M = w / m x 6.023 x 10²³
⟹ M = 0.5 / 2 x 6.023 x 10²³
⟹M = 0.25 x 6.023 x 10²³
⟹ M = 1.5 x 10²³
(3)
- Mass of O2 = 10 g
- Molar mass of O2 = 32
From the formulae we can conclude that ,
⟹ w / m = M / 6.023 x 10²³
On rearranging ,
⟹ M = w / m x 6.023 x 10²³
⟹ M = 10 / 32 x 6.023 x 10²³
⟹ M = 0.3125 x 6.023 x 10²³
⟹ M = 1.88 x 10²³
(d)
From the formulae we can conclude that ,
⟹ M / 6.023 x 10²³= V / 22.4
On rearranging ,
⟹ M = 15 / 22.4 x 6.023 x 10²³
⟹ M = 0.66 x 6.023 x 10²³
⟹ M = 3.97 x 10²³
The answer is d
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