1.. what is inorganic benzene? how it prepared?
Answers
Chemical formula: B3H6N3
Appearance: Colorless liquid
Magnetic susceptibility (χ): -49.6·10−6 cm3/mol
CAS Number: 6569-51-3
Good morning
Borazine is specially known as Inorganic benzene✌✌
Borazine Molecule - H3B3N3H3
Preparation:
Boron chloride is treated with Ammonium chloride in Chloro Benzene solvent to get B-trichloroborazine.
The chlorine atoms in B-trichloroborazine are replaced by Hydride ions to Get Borazine.
Chemical Equation:
chlorobenzene
3NH4Cl +3BCl3 ---------------------------> H3N3B3Cl3 + 9HCl
THF
H3N3B3Cl3 + 3LiBH4 ------------>H3B3N3H3 +3LiCL +3THFBH3
Properties of Borazine:
Borazine's structure is isoeelctronic with benzene.
Borazine is called as Inorganic Benzene because it has same structure like Benzene .
In Borazine , 6 carbon atoms of Benzene are replaced by Three B atoms and Three N atoms. There by total numbers of electrons in Borazine and Benzene is same
The structure is as Follows :
Check the attachment
In Borazine molecule, nitrogen is more electro negative than the boron . Nitrogen acquires partial negative charge and boron acquires partial positive charge.
Even though Borazine and Benzene have same stricture their chemical properties are different.
--> Organic benzene is C6H6 while Inorganic benzene is Borazine having chemical formula B3N3H6
---> Borazine is more reactive than Benzene
----> borazine undergoes addition reactions compared to benzene.