Question

1) why do alcohol have higher b.pt than halialkanes of similar molecular masses ?
2) why is the B.pt of either lower than isomeric alcohol ?
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Answer 1

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CHEMISTRY

Why do alcohols have higher boiling points than haloalkanes of the same molecular mass?

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ANSWER

Alcohols have higher boiling points than haloalkanes of same molecules mass because alcohols alcohol(−OH) have hydroxyl groups which involve in hydrogen bonding.As the intermolecular forces are high in hydrogen bonding,alcohols have higher boiling points than haloalkanes.

2)eathera have much lower boiling pointas compared to isomeric alcohals. this is because alocohal molecules associated while hydrogen bond while eather molecules or not

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