10 g of magnesium is burnt with 0.56 g 0, in a
closed vessel. Which reactant is left in excess
and how much? (At wt. Mg = 24; O = 16)
(AIPMT-2014
(1) Mg. 0.16 g (2) 0₂ 0.16 g
(3) Mg, 0.44 g (4) 0%, 0.28 g
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Answer:
The reaction involved is:
2Mg+O
2
⟶2MgO
Now, No. of moles of Mg =
2.4g/mol
1.0g
=0.0416 moles
No. of moles of O
2
=
32g/mol
0.56g
=0.0175 moles
1 mole O
2
consumes 2 mole Mg & gives 2 mole MgO
⇒O
2
here is limiting reagent as 0.0416 moles of Mg require 0.0208 mole of O
2
but only 0.0175 moles of O
2
given.
⇒0.0175 moles O
2
will consume 2×0.0175 moles of Mg
∴ No. of moles of Mg consumed = 0.035 moles
⇒ Remaining moles of Mg=0.0416−0.035
=0.0066 moles of Mg
As we know, 1 mole of Mg=24g
⇒0.0066 moles of Mg=24×0.006=0.1584g
∴ Amount of Mg left in excess = 0.16g
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