Chemistry, asked by kennu, 1 year ago

10 ml of gaseous hydrocarbon on combustion gives 40 ml of co2 and 50 ml of h2o. the hydrocarbon is?


Akash0501: what do you mean by hydrocarbon is?

Answers

Answered by ork
220
Provided they are all gases then the formula is going to be 
C4H10 

they key here is that 1 mole of any ideal gass occupies the same volume as 1 mole of any other ideal gas under the same conditions of temperature and pressure. So, since the same volume of any ideal gas has the same number of moles then you can treat the ratio of volumes as the ratio of moles. 

the ratio of volumes is 
10 : 40 : 50 
1 : 4 : 5 


all the Carbon from the hydrocarbon is in the CO2 
10 ml of hydrocarbon produces 40 ml CO2, 
1 : 4 ratio 
So 1 mole hydrocarbon has 4 moles Carbon 

All the H ends up in the water 
10 ml hydrocarbon produces 50 ml water, 
1 : 5 ratio, 
but also each water has 2 H atoms 
So 1 mole hydrocarbon has 10 moles Hydrogen 

which gives 
C4H10 
Answered by aditypatil71
7

 

 

first solution -

10 mL of gaseous hydrocarbon on combustion gives 40 mL of CO2

The number of C atoms in the formula unit is 40/10×1=4

and

10 mL of gaseous hydrocarbon on combustion gives 50 mL of H2O

50/10×2 =10

The hydrocarbon is C4H10

 

Second solution is:-

the ratio of volumes is  

10 : 40 : 50  

1 : 4 : 5  

all the Carbon from the hydrocarbon is in the CO2  

10 ml of hydrocarbon produces 40 ml CO2,  

1 : 4 ratio  

So 1 mole hydrocarbon has 4 moles Carbon  

All the H ends up in the water  

10 ml hydrocarbon produces 50 ml water,  

1 : 5 ratio,  

but also each water has 2 H atoms  

So 1 mole hydrocarbon has 10 moles Hydrogen  

which gives  

C4H10  

You can balance an equation for combustion of C4H10 to check the answer  

C4H10 + 13/2 O2 --> 4CO2 + 5H2O

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