Chemistry, asked by mokshit0103, 4 months ago

100ml of 0.5M H2SO4 solution is neutralized by
50ml of 0.1M NaOH and x ml of 0.1M Ca(OH)2
The value of x is
(1) 200 ml
(2) 370 ml
(3) 475 ml
(4) 405 ml

I know answer is 3 I want the complete solution​

Answers

Answered by Anonymous
38

Both Na2CO3 and NaOH are involved in the reaction:

2NaOH + H2SO4 -------------> Na2SO4 + 2H2O

Ca(OH)2 + H2SO4 -------------> CaSO4 + 2H2O

100 mL of 0.5 M H2SO4 is used.

0.1 L of 0.5 M H2SO4 is used.

molarity = (moles of H2SO4) / (liters of solution)

0.5 = (moles of H2SO4) / 0.1

moles of H2SO4 = 0.5 x 0.1 => 0.05 moles of H2SO4.

As 50 mL of 0.1 M NaOH is utilized completely.

0.05 liters of 0.1 M NaOH

0.1 = (moles of NaOH)/0.05

moles of NaOH =  0.05 x 0.1 => 0.005 moles of NaOH

First, let us try to find out how much of the H2SO4 is neutralized by 0.005 moles of NaOH.

The reaction is :  2NaOH + H2SO4 -------------> Na2SO4 + 2H2O

Thus, 2 parts of NaOH react with 1 part of H2SO4.

Hence, 2 parts of NaOH is 0.005 moles of NaOH

1 part = 0.005/2 => 0.0025 moles

Hence, 1 part of H2SO4 is 1 x 0.0025 => 0.0025 moles of H2SO4.

Hence, only 0.0025 moles of H2SO4 is neutralized.

Hence, 0.05 - 0.0025 => 0.0475 moles of H2SO4 remains in solution.

Now, we have to find the number of moles of Ca(OH)2 that neutralize 0.0475 moles of H2SO4.

The equation is :  Ca(OH)2 + H2SO4-----------> CaSO4 +2H2O

Hence, 1 part of Ca(OH)2 reacts with 1 part of H2SO4.

Hence, 1 part of H2SO4 is 0.0475 moles.

So, 1 part of Ca(OH)2 is 0.0475 moles.

So, 0.0475 moles of Ca(OH)2 should be present in the solution.

Volume = x ml => x/1000 L

Moles of solute = 0.0475 moles

Molarity = 0.1 M

Molarity = (moles of Ca(OH)2) / (liters of solution)

0.1 =  0.0475 / (x/1000)

0.1 = 0.0475 * 1000/x

0.1 = 47.5 /x

x=47.5/0.1

x= 47.5 * 10

x = 475 mL

Hence, 475 mL of 0.1 M Ca(OH)2 will be needed.

So the correct option is 3) 475 mL

Answered by bhumikabaruah20
2

Answer:

475ml

Explanation:

Both Na2CO3 and NaOH are involved in the reaction:

2NaOH + H2SO4 -------------> Na2SO4 + 2H2O

Ca(OH)2 + H2SO4 -------------> CaSO4 + 2H2O

100 mL of 0.5 M H2SO4 is used.

0.1 L of 0.5 M H2SO4 is used.

molarity = (moles of H2SO4) / (liters of solution)

0.5 = (moles of H2SO4) / 0.1

moles of H2SO4 = 0.5 x 0.1 => 0.05 moles of H2SO4.

As 50 mL of 0.1 M NaOH is utilized completely.

0.05 liters of 0.1 M NaOH

0.1 = (moles of NaOH)/0.05

moles of NaOH =  0.05 x 0.1 => 0.005 moles of NaOH

First, let us try to find out how much of the H2SO4 is neutralized by 0.005 moles of NaOH.

The reaction is :  2NaOH + H2SO4 -------------> Na2SO4 + 2H2O

Thus, 2 parts of NaOH react with 1 part of H2SO4.

Hence, 2 parts of NaOH is 0.005 moles of NaOH

1 part = 0.005/2 => 0.0025 moles

Hence, 1 part of H2SO4 is 1 x 0.0025 => 0.0025 moles of H2SO4.

Hence, only 0.0025 moles of H2SO4 is neutralized.

Hence, 0.05 - 0.0025 => 0.0475 moles of H2SO4 remains in solution.

Now, we have to find the number of moles of Ca(OH)2 that neutralize 0.0475 moles of H2SO4.

The equation is :  Ca(OH)2 + H2SO4-----------> CaSO4 +2H2O

Hence, 1 part of Ca(OH)2 reacts with 1 part of H2SO4.

Hence, 1 part of H2SO4 is 0.0475 moles.

So, 1 part of Ca(OH)2 is 0.0475 moles.

So, 0.0475 moles of Ca(OH)2 should be present in the solution.

Volume = x ml => x/1000 L

Moles of solute = 0.0475 moles

Molarity = 0.1 M

Molarity = (moles of Ca(OH)2) / (liters of solution)

0.1 =  0.0475 / (x/1000)

0.1 = 0.0475 * 1000/x

0.1 = 47.5 /x

x=47.5/0.1

x= 47.5 * 10

x = 475 mL

Hence, 475 mL of 0.1 M Ca(OH)2 will be needed.

So the correct option is 3) 475 mL

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