11. What is the value of a?
†
as
66aº
27a9
56aº
31ay
(a) 90°
(c) 180°
High Order Thinkin
(b) 10°
(d) 2°
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Answer:
Element mass % Atomic mass(g) m%/At. mass Integral ratio
Na 14.31 23 0.622 2
S 9.97 32 0.311 1
H 6.22 1 6.22 20
O 69.5 16 4.34 14
Empirical formula is therefore Na
2
SH
20
O
14
empirical mass=2×23+32+20×1+14×16=322g
Given:
Molecular mass = 322 g
∴ molecular formula =empirical formula=Na
2
SH
20
O
14
Given that all the hydrogen in the compound is reset in combination with oxygen as water of crystallisation
If water of crystallization are nH
2
O then, 2n=20
or n=10
Crystallized water is 10H
2
O remaining atoms are Na
2
SO
4
therefore, the molecule is Na
2
SO
4
.10H
2
O
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