12. a. How much potassium chlorate should be heated to produce 2.24L of oxygen at NTP?
b. 4 litres of water are added to 2L of 6 molar HCl solutions. What is the molarity of resulting solution?
c. What volume of 10M HCL and 3M HCI should be mixed to obtain 1L of 6M HCL solution?
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A:The equation is : 2KClO
3
→2KCl+3O
2
2moles→3moles
i.e. 2(39+35.5+48)→3×22.4 of oxygen
245g of KClO
3
3×22.4lit
i.e. 3×22.4 lit of O
2
→245g of KClO
3
∴2.24 lit of O
2
→
3×22.4
245
×2.24
=8.17g
B:Total volume of the solution after mixing =(4+2)=6L
By applying molarity equation :
M1V1(dilute)≡M2V2(conc.)
M1×6=6×2orM1=6×26=2M.
C:Applying molarity equation:
Therefore Vol. of 10 M HCl required = 0.428 L = 428 mL. Vol. of 3 M HCl required = 1-0.428 = 0.527 L = 572 mLRead more on Sarthaks.com - https://www.sarthaks.com/64253/what-volume-of-10-m-hcl-and-3-m-hcl-should-be-mixed-to-get-1l-of-6-m-hcl-solution
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