12. Assertion: The reaction of CH3ONa with (CH3)3CBr gives exclusively 2-Methylpropene.Reason: Alkoxides are strong bases also.
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Both assertion and reason are true.
Explanation:
The reaction is:
CH3ONa + (CH3)3CBr → 2-Methylpropene + NaBr.
- In Williamson's synthesis when Sodium methoxide reacts with t-butylbromide, 2-Methylpropene is produced exclusively as this is an example of Williamson's synthesis.
- This is because alkoxides are not only nucleophiles but strong bases also, thus leading to the elimination reaction of alkyl halides.
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