12. lonisation energy decreases on moving from lithium bowand cesium. Why?
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As mentioned before, in each of the elements Group 1, the outermost electrons experience a net charge of +1 from the center. However, the distance between the nucleus and the outer electrons increases down the group; electrons become easier to remove, and the ionization energy falls.
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Explanation:
Ionisation energy is defined as a energy required to remove outermost electron from an atom
Reason For I.E decrease when moving from Li to Cs
- In an atom, electron and proton are bound together by their electrostatic force of attraction
- If electrostatic force between electron and proton is more then that electron will be tightly bounded to an atom
- As per columb law of electrostatic force, Electrostatic force is inversely proportional to square of distance between the charges
- We know that atomic size increase from Li to Cs so the distance between outermost electron and proton also increase so their mutual Force of attraction decreases
- If Mutual force of attraction decreases then that outermost electron are loosely binded to an atom
- So if we provide a small of Energy to that outermost Electron then that electron will leave the orbital
- So I.E decreases from Li to Cs due to increase in atomic size from Li to Cs
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