13. Assertion (A): In esterification, carboncybc acid and alcohol reacts in the presence of add to
Reason (R): Esterification is the reverse of saponification
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Answer:
reason is correct
Assertion is wrong .
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Assertion (A): In esterification, carboxlic acid and alcohol reacts in the presence of concentrated sulphuric acid
Reason (R): Esterification is the reverse of saponification
Explanation:
True ,esterification is not reverse of saponification .
Saponification
It refers to preparation of soap .
Soaps are sodium salt of long hydrocarbon chain carboxylic acid .
The soaps are prepared from vegetable oil .
The reaction is given below :
Vegetable oil + NaOH ---> Soap + glycerol
After the soap is formed , a pinch of salt NaCl is added to ppt it .
Esterification
It refers to formation of esters.
the general formula for esters are RCOOR
The esters have fruity smell .
In esterification :
Alcohol + Carboxylic acid ----> Ester + water
(in presence of sulphuric acid )
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