13. Naphthalene contains 93.75% C and the rest hydrogen. Molecular mass of naphthalene is 128 Find its empirical formula. (a) C5H4 (b) C6H (c) C5H10 (d) C5
H2
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Answer:
Mass of carbon =93.71
Mass of hydrogen =6.29
Number of mole (carbon) =
12
93.71
=7.8
Number of mole (hydrogen) =
1
6.29
=6.29
Hence most simple ratio, for carbon
6.29
7.8
=1.25
for hydrogen,
6.29
6.29
=1
since, it is not a whole number we multiply the ratio by 5 to get a whole number ratio.
Lowest whole number ratio is
for carbon =5
for hydrogen =4
Empirical formula =C
5
H
4
Ratio =
64g
128g
=2
molecular formula
=2×C
5
H
4
=C
10
H
8
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