14 Calculate the arder of the reaction,
whose Rate = k[ NO)² (O₂]
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Here rate law is given as:-
rate=k[NO]2[O2]........(1)
[NO](concentration of NO) can be written as Vn
where n=number of moles and V=volume
From (1)
rate=K[Vn]2[Vn]......(2)
Now,
Volume is related to 1/3rd
From V to 3V
put new volume in (2)
New rate will be
r′=K[V3n]2[V3n]=K(3)2[Vn]2(2)[Vn]=27K[V3n]2[V3n]so,rr′=K[Vn]2[Vn
Therefore, the rate reaction changed by 27times.
I hope my answer helps you .....✌
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