17. Give the names of the reagents to bring about the following transformations.
i) Hexan-1-ol to hexanal ii) But-2-ene to ethanal
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Answer:
(i) C
5
H
5
NH+CrO
3
Cl - (PCC)C5H(i) C
5
H
5
NH
+
CrO
3
CI
−
(PCC)
(ii) Anhydrous CrO
3
(iii) CrO
3
in the presence of acetic anhydride/ CrO
2
CI
2
2.H
2
O
(iv)(Diisobutyl) aluminium hydride (DIBAL-H)
(v)PCC
(vi) O
3
/H
2
O−Zn dust
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