18. Ethanamine can be obtained from methyl
iodide by the action of alc. KCN followed by
1) hydrolysis
2) oxidation
3) reduction
4) action of NH,/heat
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Answer:
Methyl iodide is treated with NaCN to form acetonitirle. Acetonitrle is reduced with Na/ ethanol to form ethyl amine. This reaction is called Mendius reduction.
CH
3
−I+NaCN→CH
3
−CN+NaI
CH
3
−CN
Na/ethanol
CH
3
−CH
2
−NH
2
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