1g mixture of CaCO3 and Nacl reacts completely with 100ml of 0.1 N HCl .the %of CaCO3 in the mixture is
1.40%
2.60%
3.50%
4.80%
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answer: option (3) 50%
explanation : NaCl is neutral salt so, it can't react with HCl but CaCO3 reacts with HCl and forms CaCl2 compound.
To understand, see chemical reaction ....
here it is clear that , one mole of CaCO3 reacts with 2 moles of HCl.
given, normality of HCl = 0.1N so, molarity = 0.1M [ as basicity of HCl = 1]
volume of HCl solution = 120ml
so, number of mole of HCl = 0.1M × 100mL = 10 milimole or 0.010 mole
so, for 0.010 mole of HCl 0.005 mole of CaCO3 is require to complete chemical reaction.
hence, mass of CaCO3 = mole of CaCO3 × molar mass of CaCO3
= 0.005 × 100
= 0.5g
so, the mass of NaCl in mixture = 1g - 0.5g = 0.5g
now, % of CaCO3 in mixture = 0.5/(0.5+0.5) × 100 = 50%
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