2.84mL of “Chamber's acid” is made up of a litre solution. 50mL of this solution neutralize 38.2mL of N/10 Na2CO3 solution. Find the percentage of sulphuric acid in the “Chamber acid”, if its specific gravity is 1.71. [Ans: 77.08%]
Answers
Answer:
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Explanation:
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Answer:given
Volume of chamber acid(Va)=2.84ml
Volume of diluted solution(V)=1L=1000ml
Now,for nutealization
of (diluted solution). With(Na2Co3)
Volume of acid solution taken(V’)=50ml. Normality of base(Nb)=N/10
Normality of acid solution(N)=? Volume of base(Vb)=38.2ml
From principle of volumetric analysis,
NV’=NbVb
N=(NbVb)/V’
∴N=(1/10×38·2)/50=0.0764N
Then,
VaNa=NV
Na=(NV)/Va
∴Na=(0.0764×1000)/2.84=26.90N
so, we have
Normality(Na)=[(%w/w)×10×d]/E
(%w/w)=(Na×E)/(10×d)
∴(%w/w)=(26.90×49)/(10×1.71)=77.08%(Ans)
Explanation: