2. Air pressure is the highest at the sea level.
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At sea level, air pressure is greatest because it is caused by the weight of the entire column of atmosphere at that altitude over that location. As altitude increases, the column of atmosphere gets shorter, and so less weight is pressing down at a given altitude, so atmospheric pressure is reduced.
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Answer:Explaining Changes in Air Pressure with Altitude
With more gas particles in a given volume, there are more collisions of particles and therefore greater pressure. The depth (distance from top to bottom) of the atmosphere is greatest at sea level and decreases at higher altitudes.
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