2 moles each of CH3OH & CH3COOH are taken and heated in the presence of conc.H2SO4 so that
equilibrium is established. If Kc for esterification process is 4, moles of ester present at equilibrium is
1) 1.33
2) 1.6
3) 0.67
4) 0.33
Answers
Answer:
Dear Student,
CH3OH + CH3COOH −→−−−−−conc.H2SO4 CH3COOCH3 + H2O
2moles 2moles 0 mole 0 mole (at t=0)
(2-x) (2-x) x x (no. of moles at t= equilibrium)
Kc = −→−−−−−−−−−−−−[CH3OH][CH3COOH][CH3COOCH3][H2O]
= −→−−−−−−(2−x)*(2−x)x*x
4 = x2(2−x)2
Taking square root both side
2 = x(2−x)
4 - 2x = x
3x = 4
x = 43
Thus 4/3 moles of ester (CH3COOCH3) is formed.
Molar mass of ester is = 74g/mol
mass = mole * molar mass
= 43*74
=98.6g
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#ANSWER with QUALITY
CH3OH + CH3COOH −→−−−−−conc.H2SO4 CH3COOCH3 + H2O
2moles 2moles 0 mole 0 mole (at t=0)
(2-x) (2-x) x x (no. of moles at t= equilibrium)
Kc = −→−−−−−−−−−−−−[CH3OH][CH3COOH][CH3COOCH3][H2O]
= −→−−−−−−(2−x)*(2−x)x*x
4 = x2(2−x)2
Taking square root both side
2 = x(2−x)
4 - 2x = x
3x = 4
x = 43
Thus 4/3 moles of ester (CH3COOCH3) is formed.
Molar mass of ester is = 74g/mol
mass = 98.4
moles = 98.6 / 74 = 1.33