2 moles of a mixture of acetylene and ethane produced on combustion, 5500 KJ of heat energy. The
enthalpies of combustion of acetylene and ethane are 2000 and 3000 kJ mol-" respectively. The ratio of
acetylene to ethane in the mixture is
1) 1:3
2) 1:1
3) 3:1
4) 1:2
Answers
Answer:
1:3
Explanation:
Let number of moles of acetylene be and no.of moles of ethane be 1-x.
If one mole acetylene produces 2000KJ on combustion, x moles produce 2000x KJ;
Similarly, if one mole ethane produce 3000KJ then 1-x moles produce 3000(1-x) KJ energy.
Given that 2 moles of the mixture produce 5500KJ then one mole produce 2750KJ.
Now, 2000x + 3000(1-x) = 2750
On soving x=1/4 and 1-x = 3/4.
Taking the ratio = 1:3.
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Answer:
The ratio of acetylene to ethane in the mixture is 1 : 3.
Therefore, option (1) is correct.
Explanation:
Consider that 'x' is the number of moles of acetylene and '1-x' is the number of moles of ethene.
Given, for one mole enthalpies of combustion of acetylene = 2000KJ
For x moles of acetylene the enthalpies of combustion = KJ
Similarly, for one mole enthalpies of combustion of ethane = 3000 KJ
For (1-x) mole of acetylene, enthalpies of combustion = KJ
Given that 2 moles of the mixture produce heat energy = 5500KJ
Then one mole will produce heat energy = 2750KJ.
For the mixture of acetylene and ethane
Then,
The ratio of acetylene to ethane in the mixture =
Simplify, the ratio is 1 : 3
Therefore, the ratio of acetylene to ethane in the mixture is equal to 1 : 3.
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