2 moles of an ideal gas at temperature 27°C is
heated isothermally from volume V to 4V. If R = 2
cal/mol K, then the heat input in this process is
approximately
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Answered by
48
isothermal process ; ∆T = 0
so, change in internal energy , ∆U = 0
from first law of thermodynamics,
∆Q = ∆U + W
⇒∆Q = 0 + W
⇒∆Q = W
hence, heat input in this process is equal to workdone by gas.
Work done , W = P∫dV
we know, PV = nRT ⇒P = nRT/V
so, W =nRT ∫dV/V
= nRTln[V2/V1]
so, ∆Q = nRTln[V2/V1]
here, n = 2, R = 2Cal/mol.K and T = 27° = 27 + 273 = 300K , V2 = 4V, V1 = V
so, ∆Q = 2 × 2 × 300 × ln[4V/V]
= 1200ln(4)
= 2400ln(2)
= 2400 × 0.693
= 1663.2 Cal
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