2. Nitrogen forms only NCI, but phosphorous forms PCI, and PCI, both. Explain.
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Answer:
There is no vacant d-orbital in the outermost orbit of Nitrogen. ... There are valent d-orbitals in the outer most orbit of phosphorus and hence it shows variable covalence 3 and 5 in ground state and excited state respectively. Hence nitrogen forms only NCl3 but phosphorus forms PCl3 and PCl5 both
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P has the d orbital
so,
P forms PCl3,PI3,PBr3
thus,
N have no d orbital
so,
N froms only NCl3
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