20 gram of a mixture of Na2 CO3, NaHCO3 and NaCl when heated produce 1.12 litre CO2 at STP if the starting mixture is reacted with HCl ,0.3 moles of HCL are required for complete reaction find percentage of NaCl in the mixture .
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Answer:
Sodium bicarbonate decomposes in
the following manner.
2NaHCO
3
→Na
2
CO
3
+H
2
O+CO
2
Sodium Carbonate is stable and
doesn't dissociate upon normal
heating.
Vol. of CO
2
=224ml
22.4Ltr=1mole
So moles of CO
2
=0.224/22.4=0.01mole
0.01mole=44×0.01g=0.44g
1 mole CO
2
is procured by 2 mole NaHCO
3
∴ Moles of NaHCO
3
=2×0.01=0.02
=0.02×84=1.689
% age =
Totalmass
mass
×100=
2
1.68
×100=84%
solution
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