25g of a solid dibasic acid is completely neutralized by 25 ml. Of 0.25 molar ba(oh) 2 solution. Molecular mass of the acid is
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given mass of solid acid = 1.25 g [ you did mistake in typing ]
Let molecular mass of acid is M.
for complete neutralisation,
equivalent of acid = equivalent of base
or, mass of acid/equivalent weight of acid = mass of base/equivalent weight of base
or, n-factor of acid × mole of acid = n-factor of base × mole of base
or, 2 × 1.25/M = 2 × 25/1000 litre × 0.25 molar
or, M = 1000 × 1.25/(25 × 0.25)
= 125000/(625) = 200 g/mol.
hence, molecular mass = 200 g/mol
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Nice question....... Hope it helps you
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