27. Hydrate of cyclopropanone is more stable because -
(a) the angle strain in cyclopropanone hydrate decreases.
(b) sp carbon changes to sp
(c) oxygen is electron donating atom.
(d) none of these
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Explanation:
Cyclopropanone is particularly strained because the sp2 carbonyl carbon would like a bond angle of 120°—there is '60° of strain. ' In the hydrate that carbon atom is sp3 hybridized and so there is only about '49° of strain. ' Not much gain, but the hydrate is more stable than the ketone.
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Hydrate of cyclopropanone is more stable because :-
a) The angle strain in cyclopropanone Hydrate decreases.
b) sp2 carbon changes to sp3✔️✔️✔️
c) oxygen is Electron donating atom
d) none of these
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