29. Which of the following is not correct ?
(a) ∆G is zero for a reversible reaction
(b)∆Gis positive for a spontaneous reaction
(c) ∆G is negative for a spontaneous reaction
d) ∆G is positive for non-spontaneous reaction
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(b) is incorrect answer
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the correct answer for this question will be (b) ∆G is positive for a spontaneous reaction
Gibbs free energy formula to be used here is:
ΔG = ΔH – TΔS
Δ G=change in the Gibbs Free Energy
Δ H=change in the enthalpy
T=temperature measured in Kelvin
Δ S=change in the entropy
different cases in this situation depending upon the values of ΔH , ΔS and T can be as follows:
- if ΔG is less than zero then the reaction is spontaneous
- if ΔG is greater than zero then the reaction is non spontaneous
- if ΔG is equal to zero then the reaction becomes reversible
now checking the options
- (a) true statement because of (3)
- (b) wrong statement because of (1)
- (c) true statement because of (1)
- (d) true statement because of (2)
now as we have to mark the incorrect statement ,
so the correct answer is (b) ∆G is positive for a spontaneous reaction
#SPJ3
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