3 example: of reduction of aldehydes and ketones
Answers
Answer:
* Aldehydes and ketones are most readily reduced with hydride reagents
* The reducing agents LiAlH4 and NaBH4 act as a source of 4 x H- (hydride ion)
* Overall 2 H atoms are added across the C=O to give H-C-O-H
* Hydride reacts with the carbonyl group, C=O, in aldehydes or ketones to give alcohols.
* The substituents on the carbonyl dictate the nature of the product alcohol.
* Reduction of methanal (formaldehyde) gives methanol.
* Reduction of other aldehydes gives primary alcohols.
* Reduction of ketones gives secondary alcohols.
* The acidic work-up converts an intermediate metal alkoxide salt into the desired alcohol via a simple acid base reaction.
Answer:
Aldehydes and ketones are most readily reduced with hydride reagents
The reducing agents LiAlH4 and NaBH4 act as a source of 4 x H- (hydride ion)
Overall 2 H atoms are added across the C=O to give H-C-O-H
Hydride reacts with the carbonyl group, C=O, in aldehydes or ketones to give alcohols.
The substituents on the carbonyl dictate the nature of the product alcohol.
✓Reduction of methanal (formaldehyde) gives methanol.
✓Reduction of other aldehydes gives primary alcohols.
✓Reduction of ketones gives secondary alcohols.
The acidic work-up converts an intermediate metal alkoxide salt into the desired alcohol via a simple acid base reaction.
Explanation:
✓ is the examples in the above answer
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