3 free dotation around the bond exists when a bond in
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Rotation can occur because the heaviest electron density in the σ bond exists along an imaginary line between two carbon nuclei. Rotation does not change this electron distribution; the bond strength remains constant throughout rotation. Because rotation is possible, the molecule can have an infinite number of conformations, and a sketch of any of them is an accurate representation of the molecule. Some conformations have slightly higher energy content because of repulsion between atom
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