3. The least reactive compound among the following carbonyl compounds towards nucleophilic
addition reactions is
a. benzaldehyde b. p-nitrobenzaldehyde a. p-methylbenzaldehyde b. acetophenone
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Acetophenone
Explanation:
Reactivity of a carbonyl compound towards nucleophilic addition reactions depends on its e- density. e− density at carbonyl carbon increases with increase in the +I effect. This +I effect is the least in aldehydes. So Acetophenone will be the least reactive towards nucleophilic addition reactions among the given carbonyl compounds.
Order of reactivity is as follows:
Acetophenone < p-methylbenzaldehyde < Benzaldehyde < p-Nitrobenzaldehyde
Acetophenone is the answer.
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