32.05 ml of phosphorus vapour weigh 0.06225 g at 546° and 1 bar pressure .what is the molar mass of phosphorus?
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Answer:
Explanation:
p=0.1bar\\
V=34.05mL=34.05×10
−3
L=34.05×10
−3
dm
3
R=0.083bardm
3
k
−1
mol
−1
T=546°C=(546+273)K=819K
We can calculate the number of moles (n) by using the ideal gas equation : pV=nRT.
Replacing n by
M
m
, where, m=mass=0.0625g
M=Molecularmass, which we need to find.
pV=
M
mRT
So,M=
PV
mRT
=
(0.1X34.05×10
−3
)
(0.0625X0.083X819)
=1247.5gmol
−1
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