32. Select species which is planar at nitrogen :
(A) (CH3)3N (B) (SiH3)3N (C) NF3 (D) NH3
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Answer: (SiH3) 3N
Explanation:Silicon has vacant d orbitals. the lone pair on N provides the vacant d orbital of Si with electrons. Hence N-SIH3 bond gains parial double bond chracter i.e its hybridisation becomes sp2 which is trigonal planar. Imagine back bonding as a sort of resonance between lone pair and the other atom with a vacant d or p orbital
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