4. Furan on reaction with CHC13/KOH
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REACTION OF FURAN WITH CHLOROFORM IN POTASSIUM HYDROXIDE WILL FORM FURFURAL.
Explanation:
- An unsaturated hydrocarbon undergoes Reimer Teimann reaction with chloroform in presence of a base to form a carbene intermediate.
- Ortho-formylated products are formed from phenols, when they undergo Reimer Teimann reaction.
- The reaction of furan with chloroform and KOH will form a carbene intermediate first, then hydroxide ion attacks the carbon of carbene and it will lose chlorine atoms to form a ⇒ furfural.
- Therefore, reaction of furan with chloroform/KOH will give furfural.
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