43 In NaCl crystal, chloride ions present at the face center are distributed in
A. One Unit Cell
B. 8 Unit cells
C. 4 Unit cells
D. 2 Unit cells
Answers
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Explanation:
c 4 unit cells
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Answer:
4 unit cells
Explanation:
face-centred cubic
The crystalline structure of NaCl is face-centred cubic.
The total number of ions present in one unit cell of sodium chloride lattice is 8.
It includes 4 Na+ ions and 4 Cl− ions.
There are 8 Cl− ions at 8 corners of fcc unit cell (each one contributes one eigth to unit cell) and 6 Cl− ions at 6 face centres (each one contributes one half to unit cell)
Total number of Cl− ions in the unit cell =8×81+6×21=1+3=4
Na+ ions occupies octahedral voids.
There are 4 octahedral voids in fcc unit cell.
Thus, there are 4 Na+ ions in fcc unit cell.
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