44.3.42 g of sucrose are dissolved in 18 g of water in a beaker. The numbers of oxygen atoms in the solution are: (a) 6.68 ×1023 (b) 6.09 ×1022 (c) 6.022 ×1023 (d) 6.022 ×1021
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(a) 6.68 × 1023
Carbon = 12
Hydrogen = 1
Oxygen = 16
C = 12 × 12 = 144
H = 1 × 22 = 22
O = 16 × 11 = 176
Sucrose = 144 + 22 + 176 = 342 g/mol
1 mol of sucrose (C12H22O11) contains = 11× NA atoms of oxygen,
where NA = 6.023×1023
0.01 mol of sucrose (C12H22O11) contains = 0.01 × 11 × NA atoms of oxygen
= 0.11× NA atoms of oxygen
= 18 g/(1 × 2+ 16)gmol-1
=18 g /18 gmol-1
= 1mol
1mol of water (H2O) contains 1 × NA atom of oxygen
Total number of oxygen atoms = Number of oxygen atoms from sucrose + Number of oxygen atoms from water
Total number of oxygen atoms = 0.11 NA + 1.0 NA = 1.11NA
Number of oxygen atoms in solution = 1.11 × Avogadro’s number
Number of oxygen atoms in solution = 1.11 × 6.022 ×1023
Number of oxygen atoms in solution = 6.68 × 1023
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