44. In Sulfonic acid -SO3H group is
replaced by -NO2 group is called
a) Ortho substitution
d) Ipso substitution
b) Meta substitution
c) Para substitution
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☆ Answer
b ) Meta substitution
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CORRECT OPTION IS (b).
(b) META SUBSTITUTION
Explanation:
- The sulphonic acid group and nitro groups are electron withdrawing in nature.
- They tend to take up electrons from the benzene ring and deactivates it. They are usually attached to meta position of benzene ring relative to other groups attached.
- In meta substitution, substituents are present on 1, 3 positions.
- When nitro group substitutes the sulphonic group, it is called meta substitution as it is being removed from the meta position.
- Therefore, option (b) meta substitution is correct.
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