5. Calculate the change in entropy, Gibbs energy and enthalpy in the process of assimilation in the human body of sucrose, which is reduced to its oxidation.
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The relationship between the Gibbs free energy change ΔG, the enthalpy change ΔH and the entropy change ΔS is as shown.
ΔG=ΔH−TΔS But ΔH=2.0Kcal=2000.0cal ΔS=20calK
−1
T=298K
Substitute values in the above expression
ΔG=2000.0−298×20calK
−1
=−3960.0 =−ve,
hence spontaneous.
Note: For a spontaneous process, the free energy change is negative. For equilibrium process, the free energy change is zero and for non spontaneous process, free energy change is positive.
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