5. Hydrogen gas is collected over water at 27°C and 762 7mmHg pressure. If the volume of the gas collected is 0.912 L. calculate the volume of dry gas at STP. (At 27°C the vapour pressure is 26.7mmHg) -
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C
0.96 atm
Using the Dalton's law
P (Total) = Poxygen +Pwater
The vapor pressure of water is 21mmHg
751mmHg = Poxygen + 21 mmHg
Poxygen = 751 mmHg - 21 mmHg
Poxygen =730 mmHg
Convert the partial pressure of oxygen in to atmosphere
(730 mmHg) (1 atm / 760 mmHg) = 0.96 atm
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