5.
The range of radius ratio (cationic t
o anionic) for an octahedral arrangement of
ions in an ionic solid is :
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Limiting radius ratio = r/R Coordination Number of cation Structural Arrangement (Geometry of voids)
0.155-0.225 0.225-0.414 0.414-0.732 0.414-0.732 0.732-1.000 3 4 4 6 8 Plane Trigonal Tetrahedral Square planar Octahedral Cubic
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