50ml of hydrogen is collected over water at 17C and 750mm of Hg pressure. Calculate the volume of dry gas at STP. The vapour pressure of dry gas at 17C is 14mm of Hg
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1
P
1
=750mmHg−14mmHg=736mmHg
V
1
=50cm
3
,T
1
=17
0
C=290K
P
2
=760mmHg
V
2
=?cm
3
,T
2
=0
0
C=273K
Hence the Gas equation
T
1
P
1
V
1
=
T
2
P
2
V
2
290
736×50
=
273
760×V
2
∴V
2
=
290×760
736×50×273
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