54
3.
O
Identify the least stable carbocation among the following:
O
(B) H30—6=EH
(A) H3C C+
- Z
O
NH
(D)
(C)
H3C-
C+
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Answer:
The hyperconjugation involves the delocalisation of sigma electrons to the empty p orbital present at the alpha position as shown in the above image.
Hence, there is need of a sigma C−H bond of the sp
3
hybridized carbon atom which is present at alpha position with respect to the carbocation.
More the number of sigma C−H bonds at alpha position, more the number of hyperconjugating structures and more the stability. Hence structure (b) which is having nine sigma C−H bonds will be the most stable carbocation.
Explanation:
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