5g of pyrolusite (impure MnO2) was heated with conc. HCl and Cl2 evolved was passed through excess of KI solution. The iodine liberated required 40 ml of N/10 hypo solution. Find the % of MnO2in the pyrolusite.
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Explanation:
equivalent of i2 = 4
equivalent of pyrolusite = 4
moles*f*1000= 4
moles*2000=4
moles = 0.002
weight = 0.174
percentage = 0.174/5 *100
=3.48
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