6. (i) Define Schottky defect.
(ii) Copper crystallizes into a fcc lattice with edge length

Calculate the density of copper.(Atomic mass of copper = 63.5g/mol).
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Answer:
Copper crystallizes into a fcc lattice with edge length 3.61×10
−8
cm.
Fcc unit cell has 4 atoms per unit cell.
Cu has atomic mass of 63.5 g/mol.
Avogadro's number is 6.023×10
23
.
The calculated density is as below:
D=
a
3
N
0
ZM
=
(3.61×10
−8
)
3
×6.022×10
23
4×63.5
=8.97g cm
−3
This is close enough to the measured value of 8.92 g cm
−3
.
Explanation:
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