7. i.
Distinguish between esterification and
Saponification reactions of organic compounds.
With a labelled diagram describe an activity to
show the formation of an ester.
i.
Answers
Esters are most commonly formed by reaction of an acid and an alcohol. Ethanoic acid reacts with absolute ethanol in the presence of an acid catalyst to give an ester –
R’OH + RCOOH → RCOOR’ + H2O
CH3CH2OH + CH3COOH → CH3COOC2H5 + H2O
Esters are sweet-smelling substances.
Esters react in the presence of an acid or a base to give back the alcohol and carboxylic acid. This reaction is known as saponification because it is used in the preparation of soap -
RCOOR’ + NaOH → RCOONa + R’OH
CH3COOC2H5 + NaOH → CH3COONa + C2H5OH
Esters can be formed by :-
Take 1 mL ethanol (absolute alcohol) and 1 mL glacial acetic acid along with a few drops of concentrated sulphuric acid in a test tube.
Warm in a water-bath for at least five minutes as shown in Fig. 4.11.
Pour into a beaker containing 20-50 mL of water and smell the resulting mixture.
These lines have been taken from NCERT class 10 textbook
Sincerely, H S
Refer to attachments for tabular differences and activity diagram